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1/64-finals
1/32-finals
1/16-finals
1/8-finals
Quarter-finals
Semi-finals
Final
2020/21
1/64-finals
1/32-finals
| 1 | Peterhead | Stenhousemuir | 0 : 1 |
| 2 | Bye | Kilmarnock | |
| 3 | Fraserburgh | Banks O' Dee | 2 : 1 |
| 4 | Nairn County | Montrose | 1 : 7 |
| 5 | Hamilton | Bye | |
| 6 | Bye | St. Mirren | |
| 7 | Ross County | Bye | |
| 8 | Buckie Thistle | Inverness | 2 : 3 |
| 9 | Rangers | Bye | |
| 10 | Alloa | Cove Rangers | 2 : 3 |
| 11 | Celtic | Bye | |
| 12 | Arbroath | Falkirk | 1 : 2 |
| 13 | Dundee FC | Bonnyrigg Rose | 3 : 2 |
| 14 | Bye | St Johnstone | |
| 15 | Elgin City | Ayr | 0 : 4 |
| 16 | Keith | Clyde | 0 : 2 |
| 17 | Dumbarton | Huntly | 4 : 0 |
| 18 | Bye | Aberdeen | |
| 19 | Livingston | Bye | |
| 20 | Stirling | Raith | 0 : 2 |
| 21 | Forfar Athletic | Linlithgow Rose | 4 : 1 |
| 22 | Airdrieonians | Edinburgh City | 0 : 1 |
| 23 | Dundee Utd | Bye | |
| 24 | Partick Thistle | Cowdenbeath | 3 : 0 |
| 25 | Brora Rangers | Hearts | 2 : 1 |
| 26 | Kelty Hearts | Stranraer | 2 : 3 |
| 27 | Queen's Park | Queen of South | 0 : 3 |
| 28 | Bye | Hibernian | |
| 29 | Formartine Utd | Annan | 2 : 1 |
| 30 | Bye | Motherwell | |
| 31 | East Fife | Tranent | 5 : 1 |
| 32 | Morton | Dunfermline | 1 : 0 |
1/16-finals
| 1 | Stenhousemuir | Kilmarnock | 0 : 4 |
| 2 | Fraserburgh | Montrose | 2 : 4 |
| 3 | Hamilton | St. Mirren | 0 : 3 |
| 4 | Ross County | Inverness | 1 : 3 |
| 5 | Rangers | Cove Rangers | 4 : 0 |
| 6 | Celtic | Falkirk | 3 : 0 |
| 7 | Dundee FC | St Johnstone | 0 : 1 |
| 8 | Ayr | Clyde | 0 : 1 |
| 9 | Dumbarton | Aberdeen | 0 : 1 |
| 10 | Livingston | Raith | 2 : 1 |
| 11 | Forfar Athletic | Edinburgh City | 3 : 2 |
| 12 | Dundee Utd | Partick Thistle | 2 : 1 |
| 13 | Brora Rangers | Stranraer | 1 : 3 |
| 14 | Queen of South | Hibernian | 1 : 3 |
| 15 | Formartine Utd | Motherwell | 0 : 5 |
| 16 | East Fife | Morton | 1 : 2 |
1/8-finals
| 1 | Kilmarnock | Montrose | 3 : 1 |
| 2 | St. Mirren | Inverness | 2 : 1 |
| 3 | Rangers | Celtic | 2 : 0 |
| 4 | St Johnstone | Clyde | 2 : 0 |
| 5 | Aberdeen | Livingston | 3 : 2 |
| 6 | Forfar Athletic | Dundee Utd | 0 : 1 |
| 7 | Stranraer | Hibernian | 0 : 4 |
| 8 | Motherwell | Morton | 2 : 1 |
Quarter-finals
| 1 | Kilmarnock | St. Mirren | 3 : 4 |
| 2 | Rangers | St Johnstone | 1 : 2 |
| 3 | Aberdeen | Dundee Utd | 0 : 3 |
| 4 | Hibernian | Motherwell | 3 : 2 |
Semi-finals
| 1 | St. Mirren | St Johnstone | 1 : 2 |
| 2 | Dundee Utd | Hibernian | 0 : 2 |
Final
| 1 | St Johnstone | Hibernian | 1 : 0 |
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