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1/32-finals
1/16-finals
1/8-finals
Quarter-finals
Semi-finals
Final
2006/07
1/32-finals
| 1 | Kilmarnock | Bye | |
| 2 | Clyde | Queen of South | 2 : 4 |
| 3 | Brechin | Morton | 2 : 1 |
| 4 | Bye | Livingston | |
| 5 | Queen's Park | Hamilton | 2 : 1 |
| 6 | Bye | Aberdeen | |
| 7 | Partick Thistle | Dundee FC | 3 : 1 |
| 8 | Bye | Motherwell | |
| 9 | Celtic | Bye | |
| 11 | Stenhousemuir | Albion Rovers | 2 : 1 |
| 12 | Bye | St. Mirren | |
| 13 | Inverness | Bye | |
| 14 | Stirling | Dumbarton | 0 : 3 |
| 15 | Cowdenbeath | East Stirlingshire | 4 : 1 |
| 16 | Bye | Falkirk | |
| 17 | St Johnstone | East Fife | 3 : 1 |
| 18 | Arbroath | Elgin City | 0 : 1 |
| 19 | Airdrieonians | Raith | 2 : 1 |
| 20 | Bye | Dundee Utd | |
| 21 | Dunfermline | Bye | |
| 22 | Berwick | Ayr | 0 : 2 |
| 24 | Bye | Rangers | |
| 25 | Hearts | Bye | |
| 27 | Ross County | Stranraer | 4 : 2 |
| 28 | Forfar Athletic | Alloa | 1 : 2 |
| 29 | Gretna | Bye | |
| 31 | Peterhead | Montrose | 3 : 1 |
| 32 | Bye | Hibernian |
1/16-finals
| 1 | Kilmarnock | Queen of South | 2 : 1 |
| 2 | Brechin | Livingston | 0 : 3 |
| 3 | Queen's Park | Aberdeen | 1 : 0 |
| 4 | Partick Thistle | Motherwell | 2 : 3 |
| 5 | Celtic | Bye | |
| 6 | Stenhousemuir | St. Mirren | 1 : 3 |
| 7 | Inverness | Dumbarton | 3 : 1 |
| 8 | Cowdenbeath | Falkirk | 0 : 5 |
| 9 | St Johnstone | Elgin City | 4 : 0 |
| 10 | Airdrieonians | Dundee Utd | 0 : 1 |
| 11 | Dunfermline | Ayr | 1 : 0 |
| 12 | Bye | Rangers | |
| 13 | Hearts | Bye | |
| 14 | Ross County | Alloa | 1 : 2 |
| 15 | Gretna | Bye | |
| 16 | Peterhead | Hibernian | 0 : 4 |
1/8-finals
| 1 | Kilmarnock | Livingston | 2 : 1 |
| 2 | Queen's Park | Motherwell | 0 : 3 |
| 3 | Celtic | St. Mirren | 2 : 0 |
| 4 | Inverness | Falkirk | 0 : 1 |
| 5 | St Johnstone | Dundee Utd | 3 : 0 |
| 6 | Dunfermline | Rangers | 0 : 2 |
| 7 | Hearts | Alloa | 4 : 0 |
| 8 | Gretna | Hibernian | 0 : 6 |
Quarter-finals
| 1 | Kilmarnock | Motherwell | 3 : 2 |
| 2 | Celtic | Falkirk | 1 : 2 |
| 3 | St Johnstone | Rangers | 2 : 0 |
| 4 | Hearts | Hibernian | 0 : 1 |
Semi-finals
| 1 | Kilmarnock | Falkirk | 3 : 0 |
| 2 | St Johnstone | Hibernian | 1 : 3 |
Final
| 1 | Kilmarnock | Hibernian | 1 : 5 |
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