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1/32-finals
1/16-finals
1/8-finals
Quarter-finals
Semi-finals
Final
2012/13
1/32-finals
| 1 | St. Mirren | Bye | |
| 2 | Clyde | Ayr | 1 : 6 |
| 3 | Partick Thistle | Forfar Athletic | 2 : 0 |
| 4 | Annan | Hamilton | 0 : 2 |
| 5 | Dunfermline | Bye | |
| 6 | Cowdenbeath | Montrose | 1 : 2 |
| 7 | Morton | East Stirlingshire | 5 : 1 |
| 8 | Bye | Aberdeen | |
| 9 | St Johnstone | Bye | |
| 11 | Dundee FC | Peterhead | 1 : 0 |
| 12 | Airdrieonians | Queen's Park | 2 : 3 |
| 13 | Raith | Berwick | 4 : 3 |
| 14 | Bye | Ross County | |
| 16 | Bye | Celtic | |
| 17 | Inverness | Bye | |
| 18 | Stirling | Arbroath | 1 : 2 |
| 19 | Kilmarnock | Bye | |
| 20 | Brechin | Stenhousemuir | 0 : 4 |
| 21 | Motherwell | Bye | |
| 23 | Falkirk | Elgin City | 2 : 0 |
| 24 | East Fife | Rangers | 0 : 4 |
| 25 | Dundee Utd | Bye | |
| 27 | Hibernian | Bye | |
| 28 | Alloa | Queen of South | 2 : 5 |
| 29 | Livingston | Stranraer | 8 : 0 |
| 30 | Albion Rovers | Dumbarton | 0 : 2 |
| 32 | Bye | Hearts |
1/16-finals
| 1 | St. Mirren | Ayr | 5 : 1 |
| 2 | Partick Thistle | Hamilton | 0 : 1 |
| 3 | Dunfermline | Montrose | 3 : 0 |
| 4 | Morton | Aberdeen | 0 : 2 |
| 5 | St Johnstone | Bye | |
| 6 | Dundee FC | Queen's Park | 1 : 2 |
| 7 | Raith | Ross County | 4 : 1 |
| 8 | Bye | Celtic | |
| 9 | Inverness | Arbroath | 2 : 0 |
| 10 | Kilmarnock | Stenhousemuir | 1 : 2 |
| 11 | Motherwell | Bye | |
| 12 | Falkirk | Rangers | 0 : 3 |
| 13 | Dundee Utd | Bye | |
| 14 | Hibernian | Queen of South | 0 : 2 |
| 15 | Livingston | Dumbarton | 3 : 2 |
| 16 | Bye | Hearts |
1/8-finals
| 1 | St. Mirren | Hamilton | 1 : 0 |
| 2 | Dunfermline | Aberdeen | 0 : 1 |
| 3 | St Johnstone | Queen's Park | 4 : 1 |
| 4 | Raith | Celtic | 1 : 4 |
| 5 | Inverness | Stenhousemuir | 2 : 1 |
| 6 | Motherwell | Rangers | 0 : 2 |
| 7 | Dundee Utd | Queen of South | 1 : 0 |
| 8 | Livingston | Hearts | 1 : 3 |
Quarter-finals
| 1 | St. Mirren | Aberdeen | 3 : 2 |
| 2 | St Johnstone | Celtic | 0 : 5 |
| 3 | Inverness | Rangers | 3 : 0 |
| 4 | Dundee Utd | Hearts | 1 : 2 |
Semi-finals
| 1 | St. Mirren | Celtic | 3 : 2 |
| 2 | Inverness | Hearts | 1 : 2 |
Final
| 1 | St. Mirren | Hearts | 3 : 2 |
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