2016 Singles - Main
1/32-finals
| 1 | Nadal R. (1) | Bye | |
| 2 | Granollers M. | Munoz-De La Nava D. | 2 : 0 |
| 3 | Carballes Baena R. | Montanes A. (WC) | 0 : 2 |
| 4 | Bye | Sousa J. (14) | |
| 5 | Fognini F. (12) | Bye | |
| 6 | Ram R. | Youzhny M. | 0 : 2 |
| 7 | Fucsovics M. (Q) | Gulbis E. | 2 : 1 |
| 8 | Bye | Troicki V. (8) | |
| 9 | Roger-Vasselin E. (LL) | Bye | |
| 10 | Giraldo S. | Stepanek R. (Q) | 0 : 2 |
| 11 | Skugor F. (Q) | Cervantes I. | 0 : 2 |
| 12 | Bye | Kuznetsov An. (16) | |
| 13 | Kohlschreiber P. (10) | Bye | |
| 14 | Carreno-Busta P. | Istomin D. | 2 : 0 |
| 15 | Cachin P. (Q) | Dodig I. | 1 : 2 |
| 16 | Bye | Lopez F. (7) | |
| 17 | Paire B. (6) | Bye | |
| 18 | Gabashvili T. | Almagro N. | 2 : 1 |
| 19 | Ramos A. | Munar J. (WC) | 2 : 0 |
| 20 | Bye | Cuevas P. (9) | |
| 21 | Bellucci T. (15) | Bye | |
| 22 | Struff J-L. (Q) | Zverev A. | 0 : 2 |
| 23 | Jaziri M. | Chung H. | 2 : 0 |
| 24 | Bye | Olivo R. (LL) | |
| 25 | Bautista-Agut R. (5) | Bye | |
| 26 | Khachanov K. (Q) | Bedene A. | 2 : 1 |
| 27 | Bagnis F. | Donskoy E. | 0 : 2 |
| 28 | Bye | Dolgopolov A. (11) | |
| 29 | Chardy J. (13) | Bye | |
| 30 | Kukushkin M. | Estrella V. | 1 : 2 |
| 31 | De Bakker T. | Ymer E. (WC) | 2 : 1 |
| 32 | Bye | Nishikori K. (2) |
1/16-finals
1/8-finals
Quarter-finals
| 1 | Nadal R. (1) | Fognini F. (12) | 2 : 0 |
| 2 | Kuznetsov An. (16) | Kohlschreiber P. (10) | 0 : 2 |
| 3 | Paire B. (6) | Jaziri M. | 2 : 1 |
| 4 | Dolgopolov A. (11) | Nishikori K. (2) | 0 : 2 |
Semi-finals
| 1 | Nadal R. (1) | Kohlschreiber P. (10) | 2 : 0 |
| 2 | Paire B. (6) | Nishikori K. (2) | 0 : 2 |
Final
| 1 | Nadal R. (1) | Nishikori K. (2) | 2 : 0 |
2016 Singles - Qualification
Semi-finals
Final
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