2014
1/32-finals
| 1 | Atl. Nacional | La Guaira | 1 : 0, 1 : 1 |
| 2 | Cobresal | Diaz | 2 : 2, 1 : 2 |
| 3 | Sport Recife | Bye | |
| 4 | Bye | Vitoria | |
| 5 | Bahia | Bye | |
| 6 | Bye | Internacional | |
| 7 | U. Sucre | Deportes Iquique | 0 : 1, 2 : 0 |
| 8 | Millonarios | Cesar Vallejo | 2 : 2, 1 : 2 |
| 9 | Emelec | Aguilas | 2 : 1, 1 : 1 |
| 10 | U. Catolica | River Plate | 0 : 3, 0 : 1 |
| 11 | Fluminense | Bye | |
| 12 | Bye | Goias | |
| 13 | Huachipato | San Jose | 3 : 2, 3 : 1 |
| 14 | Dep. Anzoategui | U. Catolica | 1 : 2, 1 : 1 |
| 15 | Criciuma | Bye | |
| 16 | Bye | Sao Paulo | |
| 17 | Boca Juniors | Bye | |
| 18 | Bye | Rosario Central | |
| 19 | Caracas | Ayacucho | 1 : 0, 1 : 0 |
| 20 | Danubio | Dep. Capiata | 2 : 2, 1 : 3 |
| 21 | Lanus | Bye | |
| 23 | Ind. del Valle | Trujillanos | 1 : 1, 1 : 0 |
| 24 | Rentistas | Cerro Porteno | 1 : 0, 0 : 2 |
| 25 | Estudiantes L.P. | Bye | |
| 26 | Bye | Gimnasia L.P. | |
| 27 | Dep. Cali | Cajamarca | 3 : 0, 0 : 0 |
| 28 | Wilstermann | Penarol | 0 : 4, 0 : 2 |
| 29 | Libertad Asuncion | Nacional Potosi | 3 : 0, 0 : 1 |
| 30 | Alianza Lima | Barcelona SC | 0 : 0, 0 : 3 |
| 31 | Godoy Cruz | Bye | |
| 32 | Bye | River Plate |
1/16-finals
| 1 | Atl. Nacional | Diaz | 3 : 1, 0 : 2 |
| 2 | Sport Recife | Vitoria | 1 : 2, 0 : 1 |
| 3 | Bahia | Internacional | 1 : 1, 2 : 0 |
| 4 | U. Sucre | Cesar Vallejo | 0 : 3, 2 : 2 |
| 5 | Emelec | River Plate | 1 : 1, 2 : 1 |
| 6 | Fluminense | Goias | 0 : 1, 2 : 1 |
| 7 | Huachipato | U. Catolica | 0 : 1, 2 : 0 |
| 8 | Criciuma | Sao Paulo | 0 : 2, 2 : 1 |
| 9 | Boca Juniors | Rosario Central | 3 : 0, 1 : 1 |
| 10 | Caracas | Dep. Capiata | 1 : 3, 1 : 1 |
| 11 | Lanus | Bye | |
| 12 | Ind. del Valle | Cerro Porteno | 0 : 3, 1 : 0 |
| 13 | Estudiantes L.P. | Gimnasia L.P. | 1 : 0, 0 : 0 |
| 14 | Dep. Cali | Penarol | 0 : 1, 2 : 2 |
| 15 | Libertad Asuncion | Barcelona SC | 2 : 0, 0 : 1 |
| 16 | Godoy Cruz | River Plate | 0 : 2, 0 : 1 |
1/8-finals
| 1 | Atl. Nacional | Vitoria | 1 : 0, 2 : 2 |
| 2 | Bahia | Cesar Vallejo | 0 : 3, 2 : 0 |
| 3 | Emelec | Goias | 1 : 1, 1 : 0 |
| 4 | Huachipato | Sao Paulo | 2 : 3, 0 : 1 |
| 5 | Boca Juniors | Dep. Capiata | 2 : 0, 0 : 1 |
| 6 | Lanus | Cerro Porteno | 1 : 1, 1 : 2 |
| 7 | Estudiantes L.P. | Penarol | 2 : 2, 2 : 1 |
| 8 | Libertad Asuncion | River Plate | 0 : 2, 1 : 3 |
Quarter-finals
| 1 | Atl. Nacional | Cesar Vallejo | 1 : 0, 1 : 0 |
| 2 | Emelec | Sao Paulo | 3 : 2, 2 : 4 |
| 3 | Boca Juniors | Cerro Porteno | 4 : 1, 1 : 0 |
| 4 | Estudiantes L.P. | River Plate | 2 : 3, 1 : 2 |
Semi-finals
| 1 | Atl. Nacional | Sao Paulo | 1 : 1, 1 : 0 |
| 2 | Boca Juniors | River Plate | 0 : 1, 0 : 0 |
Final
| 1 | Atl. Nacional | River Plate | 0 : 2, 1 : 1 |
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